2,4-Di-tert-butyl-6-({[(R)-1-phenylethyl]amino}methyl)phenol
نویسندگان
چکیده
منابع مشابه
2,4-Di-tert-butyl-6-[1-(3,5-di-tert-butyl-2-hydroxyphenyl)ethyl]phenyl 4-methylbenzenesulfonate
The title compound, C(37)H(52)O(4)S, was obtained by the reaction of 6,6'-(ethane-1,1-di-yl)bis-(2,4-di-tert-butyl-phenol) and 4-methyl-benzene-1-sulfonyl chloride. The mol-ecular conformation is stabilized by an intra-molecular O-H⋯O hydrogen bond. Two of the tert-butyl groups are disordered over two sets of sites with occupancies 0.530 (15)/0.470 (15) and 0.615 (11)/0.385 (11).
متن کامل2,4-Di-tert-butyl-6-[(R/S)-1-(3,5-di-tert-butyl-2-hydroxyphenyl)ethyl]phenyl [(1R,4S)-7,7-dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl]methanesulfonate
The asymmetric unit of the title compound, C(40)H(60)O(5)S, comprises two diastereomers related, except for the chiral camphor groups, by a pseudo-inversion centre. In both diasteromers, the camphor sulfate moiety maintained the absolute configuartion (R,S) of the precursor. However, the absolute configurations at the methine C atoms are of opposite chirality. Both mol-ecules reveal intra-molec...
متن کامل(R)-Di-tert-butyl 1,1′-binaphthyl-2,2′-dicarboxylate
The crystal structure of the title compound, C(30)H(30)O(4), comprises two crystallographically independent half-mol-ecules which are completed by crystallographic twofold symmetry. The dihedral angles between the naphthalene ring planes are 85.83 (3) and 83.69 (3)° for the two molecules. The atoms of the tert-butyl group of one mol-ecule are disordered over two sets of sites with occupancies o...
متن کاملCrystal structure of 2,4-di-tert-butyl-6-(hydroxymethyl)phenol
The title compound, C15H24O2, is an example of a phenol-based pendant-arm precursor. In the mol-ecule, the phenol hy-droxy group participates in an intra-molecular O-H⋯O hydrogen bond with the pendant alcohol group, forming an S(6) ring. This ring adopts a half-chair conformation. In the crystal, O-H⋯O hydrogen bonds connect mol-ecules related by the 31 screw axes, forming chains along the c ax...
متن کامل3,6-Di-tert-butyl-9-(quinolin-6-yl)-9H-carbazole
In the title compound, C(29)H(30)N(2), the dihedral angle between the mean planes of the carbazole and the quinoline systems is 52.41 (6)°. Mol-ecules are linked into dimers by pairs of inter-molecular C-H⋯N hydrogen bonds and into a three-dimensional network by C-H⋯π inter-actions.
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ژورنال
عنوان ژورنال: IUCrData
سال: 2016
ISSN: 2414-3146
DOI: 10.1107/s2414314616002054